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  • 专利说明
  • 权利要求
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    • 专利摘要:
    single mode optical fiber and method for the manufacture of a single mode optical fiber. it is a single mode optical fiber that comprises from the center to the periphery a core, at least first and second compressed coatings, and an outer coat. the core has a radius (r ~ co ~) between 3.5 <109> m and an index difference with the outer coating (dn ~ co ~ -dn ~ out ~) between 0 and 3.10 ^ -3 ^ ; the first compressed coating has a radius (r ~ c11 ~) between 9 <109> m and 15 <109> m and an index difference with the outer coating (dn ~ c11 ~ -dn ~ out ~) between 5.5.10 ^ -3 ^; the second compressed coating has a radius (r ~ c12 ~) between 38 <109> m and 42 <109> m and an index difference with the first compressed coating (dn ~ c12 ~ -dn ~ c11 ~) between - 0, 5.10 ^ -3 ^ and 0.5.10 ^ -3 ^; and the outer coating has a radius between 61.5 <109> m and 63.05 <109> m. a fiber with reduced attenuation can be manufactured at a reduced cost.
    公开号:BR102012012455B1
    申请号:R102012012455-6
    申请日:2012-05-24
    公开日:2020-03-10
    发明作者:Pierre Sillard；Marianne Bigot-Astruc
    申请人:Draka Comteq B.V.；
    IPC主号:
    专利说明:

    UNIMODO OPTICAL FIBER AND METHOD FOR THE MANUFACTURE OF A UNIMODO OPTICAL FIBER
    DESCRIPTION
    The present invention relates to the field of optical fiber transmissions, and more specifically to unimode optical fibers (SMF). The invention relates to a single mode optical fiber with reduced attenuation that can be manufactured from a preform with increased capacity.
    For optical fibers, the index profile is generally classified according to the appearance of the function graph that associates the refractive index with the fiber radius. In the standard form, the distance r to the center of the fiber is shown on the x axis, and on the y axis the difference between the refractive index and the refractive index of the fiber coating. These curves are generally representative of the theoretical or stipulated profile of the fiber, whereas the constraints of fiber manufacture may result in a slightly different profile. An optical fiber conventionally consists of an optical nucleus, whose function is to transmit and possibly amplify an optical signal, and an optical coating whose function is to confine the optical signal within the nucleus. For this purpose, the refractive indices of the core n c and the outer sheath n g are such that n c > n g .
    Feed index fibers, also called SMF (single mode fibers) are typically used as line fibers for fiber optic transmission systems. These fibers have a chromatic dispersion and a chromatic dispersion slope that meet the standards
    specific to telecommunications, as well as values in cutting wavelength and area standardized effective.In response to need how much The compatibility between systems optics manufacturers
    International Telecommunication Union (ITU)
    2/21 defined a standard, reference ITU-T G.652, that a standard optical transmission fiber, called SSMF (Standard Single Mode Fiber), must satisfy.
    Among others, the G.652 standard recommends for a transmission fiber the [8.6; 9.5 pm] for Mode Field Diameter (MFD) at a wavelength of 1,310 nm; a maximum of 1,260 nm for the cable cutoff wavelength value; the range [1,300; 1.324 nm] for the zero dispersion wavelength value, denoted by λθ; a maximum of 0.092 ps / nm 2 -km for the chromatic dispersion slope value. In the standard form, the cable cut-off wavelength is measured as the wavelength at which the optical signal is no longer unimoded after propagation by twenty-two meters of fiber, as defined by the International Electrotechnical Commission subcommittee 86A IEC 60793-1-44 standard.
    Fibers with pure silica cores are also known, and are called Pure Silica Core Fibers (PSCFs). The absence of a doper in the core of a PSCF makes it possible to limit optical losses and, mainly, attenuation to a wavelength of 1,550 nm. A PSCF, therefore, conventionally has a fluorine-doped silica coating to reduce its refractive index and to ensure the function of confining the optical signal within the core.
    In a manner known per se, an optical fiber is produced by extracting a preform in a fiber extraction tower. A preform comprises, for example, a preliminary preform consisting of a glass tube of very high quality that makes up part of the coating and the fiber core. This preliminary preform is then provided with a cover coating or glove in order to increase its diameter and form a preform that can be
    3/21 used in a fiber extraction tower. The stepped fiber extraction operation consists of placing the preform vertically in a tower and extracting a fiber cord from the end of the preform. For this, a high temperature is applied locally at one end of the preform until the silica is softened; the rate of extraction of the fiber and the temperature are then permanently monitored during the extraction of the fiber, since they determine the diameter of the fiber. The geometry of the preform must perfectly satisfy the relationships of the refractive indices and the diameters of the fiber core and coating so that the extracted fiber has the required profile.
    The preliminary preform may consist of a substrate tube, usually in quartz, in which one or more layers of doped and / or non-doped silica have been deposited to form the core and an inner lining of the fiber. Deposition techniques within a substrate tube include MCVD (Modified Chemical Vapor Deposition), FCVD (Chemical Oven Vapor Deposition) or PCVD (Plasma Chemical Vapor Deposition). After depositing the layers that correspond to the core and the inner lining, the tube is closed on itself during an operation called collapse. CVD techniques ensure that the peak of OH remains low and, therefore, attenuation at 1,385 nm is limited.
    The preliminary preform can consist of a rod manufactured by external deposition techniques, such as OVD (External Vapor Deposition) or VAD (Axial Vapor Deposition). No substrate tubes are used in this case; layers of doped and / or non-doped silica are deposited by directing precursor gases and a torch to a starting rod.
    4/21
    The deposition of the components is usually indicated by the expression doping, that is, the dopers are added to the silica in order to change their refractive index. In this way, germanium (Ge) or phosphorus (P) increases the refractive index of silica; they are often used to dope the central core of the fiber. In addition, fluorine (F) or boron (B) reduces the refractive index of silica; fluorine is often used to form compressed coatings.
    The manufacture of a preliminary preform with a highly compressed and large coating is delicate. In fact, fluorine, for example, is weakly incorporated into the heated silica beyond a certain temperature, whereas a high temperature is required in the manufacture of glass. The PCVD technique can be efficiently used to produce a compressed coating within a deposition tube. Such a manufacturing technique is described in documents US RE 30,635 and US 4,314,833; it allows fluorine to be significantly incorporated into silica to form highly compressed coatings. A deposition tube, made of pure silica or doped with fluorine, is provided and mounted on a glass-making tower. The tube is then placed to rotate and a gas mixture of silica and dopers is injected into the tube. The tube crosses a microwave cavity in which the gas mixture is heated locally. Microwave heating generates plasma by ionizing the gases injected into the tube and the ionized dopans react highly with the silica particles, causing the deposition of doped silica layers within the tube. The high reactivity of the dopants, generated by microwave heating, allows a high concentration of dopants to be incorporated into the silica layers.
    5/21
    Figure 1 illustrates a stipulated index profile of a conventional PSCF. The index profile of Figure 1 shows a central core of radius R co and index Dn co that corresponds to the silica index, and an inner compressed coating of outer radius R c n and the index Dn c n. The inner lining is considered to be compressed, since it has a refractive index that is less than that of the outer lining Dn out obtained with the provision of an outer lining or a sleeve of the preliminary preform. This outer coating is generally made of pure silica glass and has substantially the same refractive index as the central core in a PSCF. Typically, the outer sheath is made of the substrate tube used to make the preliminary preform and / or the outer sheath or sleeve used to achieve the required diameter ratio.
    In the structure described above, with an external coating that has substantially the same refractive index as the central core, the fundamental mode LP01 is not completely guided and shows additional losses, called leakage. To minimize these leakage losses, the percentage of energy that propagates in the outer layer of pure silica must be reduced. The relationship between the outer radius of the fluorine-doped inner lining and the radius of the core (Rcii / Rco) must therefore be sufficiently high; that is, the silica of the inner compressed coating must be extended at least as far as a critical radius R c n whose value is dependent on the radius of the core and the difference in refractive index between the core index Dn co and the index of the inner coating Dn c n; for a standard SMF that meets the G.652 recommendation, a ratio between the radius of the compressed coating and the radius of the core which is 8 or more (R c ii / Rco> θ) is considered to ensure good signal confinement
    6/21 optical in the central core and an acceptable level of leakage losses.
    The MCVD, FCVD and PCVD techniques are satisfactory for obtaining the good quality core and the large highly compressed inner liner, but are expensive whenever high capacity preforms are sought. The capacity of a preform is defined as the proportion of the length of the optical fiber that can be extracted from that preform. The larger the diameter of the preform, the greater this capacity. To reduce manufacturing costs, it is desirable to provide long lengths of linear fiber extracted from the same preform. Therefore, what is sought is to manufacture large diameter preforms that satisfy the restrictions mentioned above with respect to the diameters of the central core and the compressed inner lining.
    US-A-2008/0031582 or US-A-5 044 724 discloses the use of a fluorine doped deposition tube to manufacture the preliminary preform. This solution allows to limit the amount of fluorine doped layers deposited inside the tube.WO-A-2010/003856 presents the manufacture of fluorine doped tubes through POD (External Plasma Deposition) or OVD.
    When a fluorine doped deposition tube is used, the compressed coating of the preliminary preform is composed of the internal deposited coating and the tube itself. The ratio between the radius of the compressed coating and the radius of the core can thereby be increased while limiting the amount of deposition within the tube. However, this solution is difficult to master for very thick tubes because deposition conditions change when a fluorine doped tube is used instead of a silica tube
    7/21 non-doped, finally limiting the reduction of the amount deposited inside the tube.
    US-A-2007/0003198 presents a hybrid process in which a rod that constitutes the Ge doped core region is produced by means of VAD or OVD and a coating region is deposited inside a tube by means of MCVD. The core rod and MCVD casing tube are then assembled using a rod-in-tube technique. However, the fibers presented in this document do not have refractive index profile structures with pure silica cores and compressed coatings, and as a result they do not have their inherent results, particularly low attenuations at 1,383 nm and 1,550 nm.
    US-A-2003/0063878 discloses a method for the manufacture of large preforms. The core and the internal linings are deposited by means of CVD in a deposition tube that is subsequently removed completely. The outer coating is deposited by external or rod-in-tube deposition methods. This document aims to control the attenuation at 1,550 nm for fibers passed to non-zero dispersion or dispersion compensation fibers.
    US-A-2004/0159124 discloses a method for the manufacture of very large preforms. The core is deposited by means of MCVD in a deposition tube that is subsequently removed completely. The doped cover liner can then be used to extend the compressed region.
    However, none of the documents above have a PSCF or slightly doped core fibers that have controlled leakage losses and reduced attenuation at 1,385 nm and 1,550 nm.
    The objective of the invention is to facilitate the manufacture of a high-capacity optical fiber preform
    8/21 while maintaining the optical quality of the fiber, mainly for PSCF or slightly doped core fibers with low attenuations at 1,385 and 1,550 nm.
    This objective is achieved with a unimoded fiber that comprises, from the center to the periphery, a core, at least first and second compressed coatings, and an external coating, in which:
    - the core has a radius between 3.5 pm and 5.5 pm and an index difference with the outer coating between 0 and 3, 10 '3;
    - the first compressed coating has a radius between 9 pm and 15 pm and an index difference with the external coating between -5.5.IO ' 3 and -2.5.10' 3.
    /
    - the second compressed coating has a radius between 38 pm and 42 pm and an index difference with the first compressed coating between 0.5.10 ' 3 and 0.5.IO'3; and
    - the outer covering has a radius between 61.5 pm and 63.5 pm.
    According to one embodiment, the fiber additionally comprises a third compressed coating located between the first and the second compressed coatings, wherein said third compressed coating has a radius between 15 pm and 25 pm, a difference in index with the first coating compressed between -0.5. IO ' 3 and 0.5.10' 3 , and an index difference with the second compressed coating comprised between -0.5.10 ' 3 and 0.5.10' 3 .
    According to the embodiment, the fiber may also comprise one or more of the following characteristics:
    - the core is made of non-doped silica;
    9/21
    - the outer coating is made of non-doped silica;
    each of the compressed coatings is made of fluorine doped silica;
    - the fiber has an attenuation at a wavelength of 1,550 nm of less than 0.18 dB / km;
    - the fiber has an attenuation in the wavelength of 1,383 nm of less than 0.35 dB / km, and more preferably of less than 0.32 dB / km;
    The invention also proposes methods for the manufacture of a unimode optical fiber according to the invention.
    According to one embodiment, a method for making the fiber of the invention comprises the steps of:
    - provision of a deposition tube;
    - carrying out the deposition of the layers within the deposition tube to constitute the core and the first compressed coating;
    - complete removal of the deposition tube;
    - provision of the second compressed coating;
    - provision of the external coating, thereby obtaining an optical preform;
    - extraction of a single mode optical fiber from said optical preform.
    The deposition tube can be made of non-doped quartz and can be removed by chemical caustication or flame polishing, or by using a mechanical technique such as grinding or polishing. A combination of these techniques can also be employed to remove the deposition tube.
    According to another embodiment, a method for making the fiber of the invention comprises the steps of:
    10/21
    - provision of a deposition tube made of fluorine doped silica;
    - carrying out the deposition of the layers within the deposition tube to constitute the core and the first compressed coating;
    - provision of the second compressed coating surrounding the deposition tube, wherein said deposition tube constitutes the third compressed coating;
    - provision of the external coating, thereby obtaining an optical preform;
    - extraction of a single mode optical fiber from said optical preform.
    The second compressed coating can be produced by one of the following: wrapping with a doped tube, cover coating with doped silica, external deposition with doped silica.
    According to another embodiment, a method for making the fiber of the invention comprises the steps of:
    - provision of a core rod by means of external deposition;
    - provision of at least two successive compressed coatings;
    provision of the outer coating, thereby obtaining an optical preform;
    - extraction of a single mode optical fiber from said optical preform.
    Each of the successive compressed coatings can be made by one of the following: wrapping with a doped tube, cover coating with doped silica, external deposition with doped silica.
    Other features and advantages of the invention will become apparent by reading the following description of the embodiments of the invention provided as examples and with reference to the figure drawings
    1, annexes that show: already described, one stipulated from a previous one;
    PSCF according to a method profile of the technical index figure
    2, a fiber profile according to a first and a third index embodiments of the invention;
    figure 3, a fiber according to a first profile and stipulated index of a third embodiment of the invention;
    profile of figure 4, a stipulated index of a fiber according to a second and third embodiments of the invention.
    The invention relates to a single mode fiber that has low low transmission losses and that can be manufactured at a reduced cost without deteriorating the propagation characteristics.
    For this purpose, the invention proposes a fiber that has a non-doped silica core fiber - or slightly doped silica core - to limit the attenuation and especially the attenuation at 1,550 nm when germanium doping is involved. Several compressed coatings are produced that surround the core. The provision of successive compressed coatings makes it possible to manufacture very large preforms at reduced costs. The position and size of the compressed sheaths are carefully chosen to minimize leakage losses of the fundamental LP01 mode, while keeping the leakage losses of the higher order LP11 mode high enough to ensure a cable cutting wavelength that meets recommendation G.652.
    12/21
    In a first embodiment, the invention proposes the production of the core and an internal compressed coating by means of CVD inside a deposition tube to limit the attenuation and mainly the attenuation at 1,383 nm due to the peak of OH; the deposition tube is then removed completely and an outer compressed coating is produced by wrapping it with a doped tube or with external deposition techniques to extend the compressed region. Such a configuration allows to reduce the width of the compressed inner lining that is deposited inside the deposition tube and to place that substrate tube closer to the central core, which results in a result of much greater capacity and much lower manufacturing costs.
    In a second embodiment, the invention proposes the production of the core and an internal compressed coating by means of CVD inside a doped deposition tube to limit the attenuation and mainly the attenuation at 1,383 nm due to the peak of OH; the compressed coating is then extended with a doped tube or with OVD or any other external deposition technique. In this embodiment, the compressed coating is composed of three different regions: a region produced with CVD inside the doped deposition tube, a region made up of the doped deposition tube and a region produced by the wrapping of the doped tube or by an external deposition technique. Such a configuration allows to reduce the width of the compressed inner lining that is deposited inside the doped deposition tube and to increase the capacity of the final preform, which results in lower manufacturing costs.
    In a third embodiment, the invention proposes the production of the core using the OVD or VAD technique to obtain a core stem. 0 first, second and possibly the
    13/21 third compressed coatings can be obtained by doped tubes wrapped like a glove over the stem of the core and / or with OVD or any other external deposition technique. In this way, the attenuation problems inherent to 1,385 nm linked to the use of VAD or OVD techniques with fluorine doped coatings are avoided.
    Figures 2 and 3 illustrate stipulated index profiles of the fibers according to the first and third embodiments of the invention. The unimode fiber of the invention comprises, from the center to the periphery, a core, a first compressed coating, a second compressed coating and an external coating. The outer coating has a Dn out index. The outer coating can be non-doped silica or slightly doped silica. The core has a radius R co between 3.5 pm and 5.5 pm and an index difference with the outer coating (Dn co -Dn or t) between 0 and 3.10 ' 3 . More preferably, the core has an index difference with the outer coating comprised between 0.5.10 -3 and 2.5.10 -3 . The slight doping - or even no doping - of the core ensures attenuation limited to 1,550 nm. In the embodiment of Figure 2, the core has substantially the same index as the outer coating. In this case, the core and / or the outer shell can be made of non-doped silica or slightly doped silica, or co-doped silica. In the realization of Figure 3, the core has an index that is slightly higher than the outer coating. In this case, the core can be made of slightly doped silica or co-doped silica, and the outer sheath can be made of non-doped silica to minimize costs.
    The first compressed coating has a radius R c ii between 9 pm and 15 pm and a difference in index (Dn c n-Dn out ) with the outer coating between 5.5.10 -3 and -2.5.10 -3 . The small radius of the first coating
    14/21 compressed - compared to the radius of the internal compressed coating of the prior art in Figure 1 - ensures limited deposition by means of CVD and cost control. If only two compressed linings comprise the compressed region (as shown in Figures 2 and 3), then the second compressed liner has a radius R c i 2 between 38 pm and 42 pm and an index difference with the outer liner ( Dn c i 2 -Dn or t) such that the difference in index between the first compressed coating and the second compressed coating (Dn c i 2 -Dn c n) is between 0.5.10 -3 and 0.5.10 -3 .
    Figure 4 illustrates the stipulated index profile of a fiber according to the second and third embodiments of the invention. In accordance with this embodiment, a third compressed coating is provided between the first and the second compressed coatings. When three compressed linings make up the compressed region (as shown in Figure 4), then the third compressed liner has a radius R c i 3 between 15 pm and 25 pm, that is, the third compressed liner is added between the first compressed coating having a radius between 9 pm and 15 pm and the second compressed coating having a radius between 38 pm and 42 pm. The third compressed coating has an index difference (Dn c i 3 -Dn out ) with the outer coating such that its difference in coating index for both the first and the second compressed coatings (Dn c i 3 -Dn c n Dn c i 3 -Dn c i 2 ) is between -0.5.10 'and 0.5.10.
    The size and content of the second - and third - compressed coating are chosen with respect to the radius and content of the first - and second compressed coating to limit leakage loss and
    15/21 ensure the cutting wavelength that meets the G.652 recommendation.
    The external coating is obtained by providing a covering coating with silica-based material or wrapping with a quartz tube or by any external deposition techniques. For example, APVD (Plasma and Advanced Vapor Deposition) can be used to produce the outer coating. The fiber has a standardized outer diameter with the outer coating having a radius R or t of 62.5 μπι ± 1 pm.
    According to a first embodiment, the fiber of the invention with two compressed coating regions (as shown in Figures 2 or 3) can be manufactured as follows.
    The core and the first compressed coating are obtained by deposition within a deposition tube and the second compressed coating is obtained by wrapping with a doped tube or by employing external deposition techniques. The viscosity and / or index values in the first compressed coating can therefore be different from the viscosity and / or index values in the second compressed coating.
    More specifically, a deposition tube is provided and the core and the first compressed coating of the fiber are deposited by means of CVD into said tube. The tube is then removed completely after the deposition of the core and the first compressed coating is completed. Therefore, it is possible to use a non-doped quartz tube to perform CVD under controlled parameters. Notably, the core and the first compressed coating can be deposited by means of PCVD or MCVD or FCVD. The tube can be removed after deposition is completed by chemical etching and / or mechanical polishing.
    16/21
    Once the deposition tube has been removed, the core and the first compressed liner are wrapped with a doped tube, for example, a fluorine doped tube. The fluorine doped tube is known, for example, from WO-A-2010/003856, US-A-2008/0031582 or USA-5,044,724. However, these documents teach the use of such fluorine doped tubes for internal deposition.
    The wrapping with a doped tube allows to extend the compressed region of the preform by constituting a second compressed coating. Only the first compressed coating, closest to the core, was deposited by means of CVD, and the second compressed coating is added by the provision of a glove. The amount of CVD deposition is limited and the cost of the preform is reduced while a large compressed region is obtained. The preform is finally overlaid with silica-based material or wrapped with the quartz tube to achieve the required diameter ratio. The cover coating will be preferred in the case of large preforms for cost control.
    According to a second embodiment, the fiber of the invention with three compressed coating regions (as shown in Figure 4) can be manufactured as follows.
    The core and the first compressed coating are obtained by deposition within a doped deposition tube that constitutes the third compressed coating, and the second compressed coating is obtained by being wrapped with a doped tube or by employing external deposition techniques. As in the second embodiment, the first compressed coating, closest to the core, can be deposited by means of PCVD or MCVD or FCVD. The amount of deposition
    17/21
    CVD is limited and the cost of the preform is reduced while a large compressed region is obtained.
    The fluorine doped tube is known, for example, from WO-A-2010/003856, US-A-2008/0031582 or US-A-5,044,724. If these documents teach the use of such fluorine-doped tubes for internal deposition, there is no indication as to an additional compressed coating surrounding the deposition tube that significantly increases the capacity of the final result. The preform is finally overlaid with silica-based material or wrapped with a quartz tube to achieve the required diameter ratio. The cover coating will be preferred in the case of large preforms for cost control.
    According to a third embodiment, the fiber of the invention with two or three regions of compressed coating (as illustrated in Figures 2, 3 and 4) can be manufactured using external deposition techniques and / or doped tubes to obtain the first, second and third compressed coatings. The viscosity and / or index values on each compressed coating, therefore, may differ from the viscosity and / or index values on the other compressed coating.
    More specifically, a core rod can be obtained through OVD or VAD; each compressed coating can be obtained by any external deposition technique or wrapping with a doped tube; and an outer coating can be obtained by overlaying it with silica-based material (for example, by means of APVD) or wrapping it with a quartz tube to achieve the required diameter ratio.
    Table I below provides examples of profiles stipulated for fibers according to the invention (Examples 1
    18/21 to 5), profiles stipulated for fibers outside the scope of the invention (Examples 2b and 3b) and a comparative example (a profile stipulated as illustrated in Figure 1).
    Table I
    Profiles & co(μm) Rcii(pm) Rc13(pm) Rc12(pm) Rout(pm) Dn co .10 ' 3 at 633 nm Diicn. 10 3 at 633 nm Dncl3.10 -3 at 633 nm Driciz 1 θ 3 at 633 nm ExampleComparative 4,35 41.00 -62.50 0.0 -5.2 - - Example 1 4,35 15.00 - 41.00 62.50 0.5 -4.7 - -4.5 Example 2 4,35 13.80 - 41.00 62.50 2.2 -3.0 - -3.4 Example 2b 4,35 13.80 - 41.00 62.50 2.2 -3.0 - -4.0 Example 3 4,35 9.50 - 39.00 62.50 2.2 -3.0 - -3.0 Example 3b 4,35 9.50 - 39.00 62.50 2.2 -3.0 - -2.4 Example 4 4,50 15.00 - 40.00 62.50 1.0 -4.5 - -4.5 Example 5 4,35 15.00 22.00 41.00 62.50 0.5 -4.7 -4.6 -4.5
    Table II below shows the optical characteristics of the fibers in the seven examples and the comparative example described above.
    Table II
    Profiles Xcc 2W02 a 2W02 a D to 1150 S to 1150 ZDW S to ZDW Loss
    19/21
    (nm) 1310 nm (pm 2 ) 1150 nm (pm 2 ) nm (ps / nm 2. km) nm (ps / nm 2. km) (nm) (os / nm 2. km) leakage at 1550 nm (dB / km) Example 1240 9.2 10.3 16.3 0.056 1315 0.086 0.001 Compar. Ex. 1 <1260 9.1 10.3 16.2 0.055 1306 0.083 0.006 Ex. 2 <1260 9.1 10.3 16.4 0.056 1309 0.084 0.001 Ex. 2b > 1400 9.1 10.3 16.4 0.057 1309 0.084 0.000 Ex. 3 <1260 9.1 10.3 16.3 0.056 1309 0.084 0.000 Ex. 3b <1260 9.1 10.3 15.6 0.053 1312 0.082 > 0.1 Ex. 4 <1260 9.1 10.2 17.1 0.056 1300 0.086 0.001 Ex. 5 <1260 9.1 10.3 16.2 0.055 1306 0.083 0.005
    Table III below shows the losses and attenuation of fiber fold in the seven examples and the comparative example described above.
    Table III
    Profiles Loss in Loss in Loss in Attenuation Attenuationmacro-fold The macro-fold The mcrodobra The 1550 nm 1383 nm1550 nm Rc = 1650 nm Rc = 1625 nm Rc = (dB / km) (dB / km)10 mm 10 mm 30 mm (dB / turn)(dB / turn)(dB / 100 turns) Example 0.20.7<0.05<0.18 <0.32 compar. Ex. 1 0.8 2.6 <0.05 <0.18 <0.32 Ex. 2 0.1 0.3 <0.01 <0.18 <0.35 Ex. 2b <0.05 <0.1 <0.01 <0.18 <0.35 Ex. 3 0.4 1.1 <0.05 <0.18 <0.35
    20/21
    Ex. 3b > 1 > 5 > 1 > 0.19 > 0.35 Ex. 4 0.09 0.3 <0.01 <0.18 <0.32 Ex. 5 0.8 2.6 <0.05 <0.18 <0.32
    Examples 2b and 3b are outside the scope of the invention because the difference in index between the first and ο second compressed coatings (Dn c i 2 - Dn c n) is too high, that is, greater than +0.5.10 - 3 . It is apparent from Table II that Example 2b has a shear wavelength that does not meet the G.652 recommendation and that Example 3b has high leakage losses, high bend losses and high attenuation.
    It can be seen from Table II that the fibers of the invention completely satisfy the above mentioned G.652 standard. It can also be seen from Table II that leakage loss is controlled in the fibers of the invention.
    It can be seen from Table III that the loss of macrod fold is controlled in the fibers of the invention. The fiber of the invention, therefore, can be used in fiber optic systems for the user. Table II also shows that the attenuation of the fibers of the invention is limited, and mainly the attenuation at 1,383 nm. The attenuation at 1,550 nm is less than 0.18 dB.km and the attenuation at 1,383 nm is less than 0.35 dB / km or even less than 0.32 dB / km. The use of a quartz tube to deposit a slightly doped silica core makes it possible to reduce the OH peak and removal of the deposition tube does not impair the optical characteristics of the fiber.
    The fiber of the invention can be manufactured from a large capacity preform. For a deposition tube with a cross sectional area of 18 0 mm 2 18 0 that results in a first radius R c n of the coating
    21/21 compressed 10 mm after collapse, final preforms with an outside diameter of 83.3 mm were obtained for Examples 1, 4 and 5; a final preform with an outside diameter of 90.6 mm was obtained for Example 2; and a final preform with an external diameter of 131.6 mm was obtained for Example 3.
    As a comparison, when the deposition tube is kept as part of the outer covering (comparative example), a final preform with an external diameter of 30.5 mm is obtained, and when the deposition tube is doped and used without any 10 additional compressed coating, resulting in the end of the compressed coating at a radius of 12.5 mm after collapse (equivalent to 40 pm in the fiber), a final result of an external diameter of 39 mm is obtained. The fiber of the invention, therefore, can be manufactured at a minimized cost.
    Certainly, the width of the compressed coating deposited within the deposition tube (R c ii) can be much smaller with the stipulated profile of the fiber of the invention.
    It should be noted that the present invention is not limited to the embodiments described as examples.
    In particular, the profiles stipulated in the figures are provided by way of example and the manufacturing methods described are not limiting.
    权利要求:
    Claims (5)
    [1]
    1. FIBER UNIMODO OPTICS featured per understand from the center to the periphery one core, at any less first and second coatings pills, it is a
    external coating, where:
    - the core has a radius (R co ) between 3.5 pm and 5.5 pm and a difference in refractive index with the external coating (Dnco-Dnout) between 0 and 3.10 -3 ;
    - the first compressed coating has a radius (R cl1 ) between 9 pm and 15 pm and a difference in refractive index with the external coating (Dncl1-Dnout) between -5.5.10 -3 and -2.5.10 -3 ;
    - the second tablet coating has a radius (R cl2) 3 between 8 pm and 42 pm and a refractive index difference with the first tablet coating (Dn Cl2 -dn CL1) -0,5.10 between -3 and 0, 5.10 -3 ; and
    - the outer covering has a radius between 61.5 pm and 63.5 pm.
    1/4
    [2]
    2/4
    2. FIBER according to claim 1, characterized in that it additionally comprises a third compressed coating located between said first and second compressed coatings, wherein said third compressed coating has a radius (Rcl3) between 15 pm and 25 pm, a difference in refractive index with the first compressed coating (Dncl3-Dncl1) between 0.5.10 -3 and 0.5.10 -3 and a difference in refraction index with the second compressed coating (Dncl3-Dncl2) between -0 , 5.10 -3 and 0.5.10 -3 .
    [3]
    3/4
    11. METHOD according to claim 9 or 10, characterized in that the removal of the deposition tube is done by chemical caustication or flame polishing, or grinding or polishing, or a combination of these.
    12. METHOD FOR MANUFACTURING A FIBER OPTIC UNIMODO characterized by having the characteristics as defined in claim 2, in which the method comprises the steps of:
    - provision of a deposition tube made of fluorine doped silica;
    - carrying out the deposition of the layers within the deposition tube to constitute the core and the first compressed coating;
    - provision of the second compressed coating surrounding the deposition tube, wherein said deposition tube constitutes the third compressed coating;
    - provision of the external coating, thereby obtaining an optical preform;
    - extraction of a single mode optical fiber from said optical preform.
    13. METHOD according to any one of claims 9 to 12, characterized in that the second compressed coating is produced by one of the following: wrapping with a doped tube, cover coating with doped silica, external deposition with doped silica.
    14. METHOD FOR MANUFACTURING A FIBER OPTIC UNIMODO characterized by having the characteristics as defined in any one of claims 1 to 8, in which the method comprises the steps of:
    - provision of a stem of the nucleus By means of external deposition;
    - provision of at least two successive compressed coatings;
    FIBER according to either claim 1 or claim 2, characterized in that the core is made of non-doped silica.
    [4]
    4/4
    - provision of the external coating, thereby obtaining an optical preform;
    - extraction of a single mode optical fiber from said optical preform.
    FIBER according to any one of claims 1 to 3, characterized in that the outer coating is made of non-doped silica.
    FIBER according to any one of claims 1 to 4, characterized in that each of the compressed coatings is made of fluorine doped silica.
    6. FIBER, in wake up with any one of claims 1 to 5, characterized in that has a mitigation to length wave in 1,550 nm less than 0.18 dB / km. 7. FIBER, in wake up with any one of claims 1 to 6, characterized in that has a mitigation to length wave in 1,383 nm less than 0.35 dB / km. 8. FIBER, in wake up with any one of claims 1 to 7, characterized in that has a mitigation to length wave in 1,383 nm less than 0.32 dB / km.
    9. METHOD FOR MANUFACTURING AN OPTICAL FIBER
    UNIMODO characterized by having the characteristics as defined in any one of claims 1 to 8, wherein the method comprises the steps of:
    - provision of a deposition tube;
    - carrying out the deposition of the layers within the deposition tube to constitute the core and the first compressed coating;
    - complete removal of the deposition tube;
    - provision of the second compressed coating;
    - provision of the external coating, thereby obtaining an optical preform;
    - extraction of a single mode optical fiber from said optical preform.
    10. METHOD, according to claim 9, characterized in that the deposition tube is made of non-doped quartz.
    [5]
    15. METHOD, according to claim 14, characterized in that each of the successive compressed coatings is produced by one of the following: wrapping with a doped tube, cover coating with doped silica, external deposition with doped silica.
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    同族专利:
    公开号 | 公开日
    CN102798927B|2016-04-27|
    DK2527893T3|2013-12-16|
    CN102798927A|2012-11-28|
    JP6008575B2|2016-10-19|
    EP2527893B1|2013-09-04|
    AU2012203014B2|2013-12-05|
    AU2012203014A1|2012-12-13|
    AR086566A1|2014-01-08|
    BR102012012455A2|2013-11-05|
    ES2438173T3|2014-01-16|
    JP2012247780A|2012-12-13|
    EP2527893A1|2012-11-28|
    US20120301093A1|2012-11-29|
    US8798423B2|2014-08-05|
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    法律状态:
    2013-11-05| B03A| Publication of a patent application or of a certificate of addition of invention [chapter 3.1 patent gazette]|
    2018-12-11| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2019-10-08| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|
    2020-01-28| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2020-02-11| B09W| Correction of the decision to grant [chapter 9.1.4 patent gazette]|Free format text: RETIFIQUE-SE, POR INCORRECOES NO QUADRO I DO PARECER |
    2020-03-10| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 24/05/2012, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    NLEP11305654.3|2011-05-27|
    EP11305654.3A|EP2527893B1|2011-05-27|2011-05-27|Single mode optical fiber|
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